Displacement reaction of thiophenol on 1-bromooctane by phase transfer catalysis through liquid-liquid flat interface.
نویسندگان
چکیده
منابع مشابه
Synthesis of 1-(isopentyloxy)-4-nitrobenzene under ultrasound assisted liquid-liquid phase-transfer catalysis
In this paper, we report the reaction of isoamyl alcohol and 1-chloro-4-nitrobenzene was carried out in a batch reactor under aqueous-organic biphasic conditions using the techniques like phase transfer catalysis and ultrasound irradiation. Tetrabutylammonium bromide (TBAB) was employed as the phase transfer catalyst. The reaction is greatly enhanced by adding a small quantity of phase-transfer...
متن کاملSelective Oxidation of Lauryl Alcohol to Lauraldehyde under Liquid-Liquid Phase Transfer Catalysis (LL-PTC) with Potassium Chromate as the Oxidizing Agent
In the present research, the selective oxidation of lauryl alcohol to lauraldehyde was studied under liquid-liquid phase transfer conditions using potassium chromate (K2CrO4) as an oxidizing agent and tetrabutyl ammonium bromide (TBAB) as the phase transfer catalyst. Chromium (VI) reagents are used in these oxidations since the alcohols are selectively oxidized <e...
متن کاملIdentifiability Analysis of a Liquid-liquid Phase-transfer Catalyzed Reaction System
Identifiability is a structural property of mathematical models. A model is identifiable if the model parameters can be uniquely identified from input-output behaviour. This work focuses on the application of a novel methodology for testing differential algebraic equation systems for identifiability. In this work, a non-linear, differential algebraic model of a liquid-liquid phase-transfer reac...
متن کاملCrystal templating through liquid-liquid phase separation.
Controlled induction of crystal nucleation is a highly desirable but elusive goal. Attempts to speed up crystallization, such as high super saturation or working near a liquid-liquid critical point, always led to irregular and uncontrollable crystal growth. Here, we show that under highly nonequilibrium conditions of spinodal decomposition, water crystals grow as thin wires in a template-less f...
متن کاملLiquid-gated interface superconductivity on an atomically flat film.
Liquid/solid interfaces are attracting growing interest not only for applications in catalytic activities and energy storage, but also for their new electronic functions in electric double-layer transistors (EDLTs) exemplified by high-performance organic electronics, field-induced electronic phase transitions, as well as superconductivity in SrTiO(3) (ref. 12). Broadening EDLTs to induce superc...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: KAGAKU KOGAKU RONBUNSHU
سال: 1987
ISSN: 0386-216X,1349-9203
DOI: 10.1252/kakoronbunshu.13.788